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mycocyclosin
An organic heterotetracyclic compound obtained via intramolecular oxidative aromatic coupling of cyclo(L-tyrosyl-L-tyrosyl).

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03. Biological Effects of Specific Chemicals

			biochemical uses [CHEBI:52206] (3306)

				metabolite [CHEBI:25212] (2692)

					secondary metabolite [CHEBI:26619] (2225)

mycocyclosin [CHEBI:71596] (1)

04. Bioactive Capabilities of Specific Chemicals

			Oxidoreductases [EC:1] (1697)

				Acting on paired donors, with incorporation or reduction of molecular oxygen [EC:1.14] (587)

					With NADH or NADPH as one donor, and the other dehydrogenated [EC:1.14.21] (28)

						Mycocyclosin synthase [EC:1.14.21.9] (7)

mycocyclosin [CHEBI:71596] (1)

08. Chemical Category

			main group molecular entity [CHEBI:33579] (25650)

					s-block molecular entity [CHEBI:33674] (7287)

							hydrogen molecular entity [CHEBI:33608] (6932)

								hydroxides [CHEBI:24651] (5641)

									organic hydroxy compound [CHEBI:33822] (3050)

phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

					p-block molecular entity [CHEBI:33675] (25343)

						pnictogen molecular entity [CHEBI:33302] (10027)

								nitrogen molecular entity [CHEBI:51143] (7930)

									amide [CHEBI:32988] (1863)

primary amide [CHEBI:33256] (1586)

carboxamide [CHEBI:37622] (1381)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

									organonitrogen compound [CHEBI:35352] (6705)

carboxamide [CHEBI:37622] (1381)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic amino compound [CHEBI:50047] (2472)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

						chalcogen molecular entity [CHEBI:33304] (15225)

								oxygen molecular entity [CHEBI:25806] (14414)

hydroxides [CHEBI:24651] (5641)

organic hydroxy compound [CHEBI:33822] (3050)

phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

organooxygen compound [CHEBI:36963] (11352)

carboxamide [CHEBI:37622] (1381)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

								organochalcogen compound [CHEBI:36962] (11874)

									organooxygen compound [CHEBI:36963] (11352)

carboxamide [CHEBI:37622] (1381)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

						carbon group molecular entity [CHEBI:33582] (23847)

							organic molecular entity [CHEBI:50860] (23769)

								heteroorganic entity [CHEBI:33285] (15197)

organic heterocyclic compound [CHEBI:24532] (5243)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

organonitrogen compound [CHEBI:35352] (6705)

carboxamide [CHEBI:37622] (1381)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic amino compound [CHEBI:50047] (2472)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organochalcogen compound [CHEBI:36962] (11874)

organooxygen compound [CHEBI:36963] (11352)

carboxamide [CHEBI:37622] (1381)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

								organic hydroxy compound [CHEBI:33822] (3050)

phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

								organic amino compound [CHEBI:50047] (2472)

peptide [CHEBI:16670] (730)

cyclic peptide [CHEBI:23449] (75)

homodetic cyclic peptide [CHEBI:24613] (46)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

oligopeptide [CHEBI:7755] (479)

dipeptide [CHEBI:46761] (253)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

								organic molecule [CHEBI:72695] (11399)

									organic cyclic compound [CHEBI:33832] (7633)

organic heterocyclic compound [CHEBI:24532] (5243)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

organic aromatic compound [CHEBI:33659] (3593)

phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

			polyatomic entity [CHEBI:36357] (18777)

				molecule [CHEBI:25367] (11520)

						cyclic compound [CHEBI:33595] (7817)

								polycyclic compound [CHEBI:33635] (4078)

heteropolycyclic compound [CHEBI:33671] (2613)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

								aromatic compound [CHEBI:33655] (3799)

organic aromatic compound [CHEBI:33659] (3593)

phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

								monocyclic compound [CHEBI:33661] (2007)

heteromonocyclic compound [CHEBI:33670] (2004)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

								organic cyclic compound [CHEBI:33832] (7633)

organic heterocyclic compound [CHEBI:24532] (5243)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

organic aromatic compound [CHEBI:33659] (3593)

phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

								heterocyclic compound [CHEBI:5686] (5275)

									organic heterocyclic compound [CHEBI:24532] (5243)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

									heteromonocyclic compound [CHEBI:33670] (2004)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

									heteropolycyclic compound [CHEBI:33671] (2613)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

						organic molecule [CHEBI:72695] (11399)

							organic cyclic compound [CHEBI:33832] (7633)

								organic heterocyclic compound [CHEBI:24532] (5243)

organic heteromonocyclic compound [CHEBI:25693] (2004)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organonitrogen heterocyclic compound [CHEBI:38101] (3202)

piperazines [CHEBI:26144] (111)

piperazinone [CHEBI:46846] (14)

2,5-diketopiperazines [CHEBI:65061] (13)

mycocyclosin [CHEBI:71596] (1)

organic heteropolycyclic compound [CHEBI:38166] (2613)

organic heterotetracyclic compound [CHEBI:38163] (128)

mycocyclosin [CHEBI:71596] (1)

								organic aromatic compound [CHEBI:33659] (3593)

									phenols [CHEBI:33853] (868)

polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

				heteroatomic molecular entity [CHEBI:37577] (13672)

					hydroxides [CHEBI:24651] (5641)

						organic hydroxy compound [CHEBI:33822] (3050)

							phenols [CHEBI:33853] (868)

								polyphenol [CHEBI:26195] (189)

mycocyclosin [CHEBI:71596] (1)

ChEBI Compound Accession Identifier:

[CHEBI:71596]

ChEBI Compound Description:

An organic heterotetracyclic compound obtained via intramolecular oxidative aromatic coupling of cyclo(L-tyrosyl-L-tyrosyl).

ChEBI Compound Identification Number:

71596

ChEBI InChI Value:

InChI=1S/C18H16N2O4/c21-15-3-1-9-5-11(15)12-6-10(2-4-16(12)22)8-14-18(24)19-13(7-9)17(23)20-14/h1-6,13-14,21-22H,7-8H2,(H,19,24)(H,20,23)/t13-,14-/m0/s1

ChEBI InChIKey Value:

PYDUENRHWXNYLP-KBPBESRZSA-N

ChEBI Compound Name:

mycocyclosin

ChEBI SMILES Value:

Oc1ccc2C[C@@H]3NC(=O)[C@H](Cc4ccc(O)c(c4)-c1c2)NC3=O

ChEBI Substance ID:

160713483

ChEBI URL:

ChEBI:71596

ChemSpider ID:

27444986

Ontomatica Chemical Accession Key (OnChAKey):

PYDUENRHWXNYLP_KBPBESRZSA_N_000_000000

PubChem Compound ID:

59053147