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clethodim
"An oxime O-ether resulting from the formal conversion ot the acyclic keto group of 5-[2-(ethylsulfanyl)propyl]-3-hydroxy-2-propionylcyclohex-2-en-1-one to the corresponding oxime with subsequent O-alkylation of the oxime by an (E)-3-chloroallyl group. It is used as a selective postemergence herbicide for the control of annual and perennial grasses in numerous crops, including alfalfa, celery, clover, conifers, cotton, cranberries, garlic, onions, ornamentals, peanuts, soybeans, strawberries, sugarbeet, sunflowers, and vegetables; the (-)-enantiomer has been reported to be more active than the (+)-enantiomer."

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02. Food Pesticide Chemicals with Regulated Residues on Food Commodities: A. Primary Food Commodities of Plant Origin > Crop Group 01 : Root & Tuber Vegetables Group > Crop Group 01 Subgroup 1C : Tuberous & corm vegetables subgroup > Crop Group 01 Subgroup 1C : Tuberous & corm vegetables subgroup: Representative Commodities
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05. Industrial Uses: pesticide [CHEBI:25944] > herbicide [CHEBI:24527] > clethodim [CHEBI:70721]
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02. Food Pesticide Chemicals with Regulated Residues on Food Commodities 
02. Food Pesticide Chemicals with Regulated Residues on Food Commodities
 B. Primary Food Commodities of Animal Origin (67) 
 Egg (37)
 Milk (61)
 Cattle (65) 
 Cattle, fat (61)
 Cattle, meat (59)
 Cattle, meat byproducts (57)
 Goat (61) 
 Goat, fat (57)
 Goat, meat (56)
 Goat, meat byproducts (55)
 Hog (48) 
 Hog, fat (44)
 Hog, meat (42)
 Hog, meat byproducts (41)
 Horse (61) 
 Horse, fat (57)
 Horse, meat (54)
 Horse, meat byproducts (55)
 Poultry (37) 
 Poultry, fat (34)
 Poultry, meat (32)
 Poultry, meat byproducts (32)
 Sheep (61) 
 Sheep, fat (57)
 Sheep, meat (56)
 Sheep, meat byproducts (55)
 A. Primary Food Commodities of Plant Origin  (98) 
 Crop Group 00 : Miscellaneous commodities intentionally not included in any group include: (67) 
 Asparagus (23)
 Globe Artichoke (19)
 Peanut (30)
 Crop Group 01 : Root & Tuber Vegetables Group (54) 
 Crop Group 01 Subgroup 1A : Root vegetables subgroup (34) 
 Crop Group 01 Subgroup 1A : Root vegetables subgroup: Representative Commodities (27) 
 Sugar beet, root (20)
 Crop Group 01 Subgroup 1A : Root vegetables subgroup: Commodities (33) 
 Sugar beet, root (20)
 Crop Group 01 Subgroup 1B : Root vegetables (except sugar beet) subgroup (28) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 01 Subgroup 1B : Root vegetables (except sugar beet) subgroup (8)
 Crop Group 01 Subgroup 1C : Tuberous & corm vegetables subgroup (45) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 01 Subgroup 1C : Tuberous & corm vegetables subgroup (16)
 Crop Group 01 Subgroup 1C : Tuberous & corm vegetables subgroup: Representative Commodities (33) 
 Potato (33)
 Crop Group 01 Subgroup 1C : Tuberous & corm vegetables subgroup: Commodities (35) 
 Potato (33)
 Crop Group 02 : Leaves of Root & Tuber Vegetables (Human Food or Animal Feed) Group (31) 
 Crop Group 02 : Leaves of Root & Tuber Vegetables (Human Food or Animal Feed) Group: Representative Commodities (19) 
 Sugar beet, leaves (19)
 Crop Group 02 : Leaves of Root & Tuber Vegetables (Human Food or Animal Feed) Group: Commodities (25) 
 Sugar beet, leaves (19)
 Radish, leaves (7)
 Crop Group 03 : Bulb Vegetables { Allium spp. } Group (14) 
 Crop Group 03 : Bulb Vegetable { Allium spp. } Group: Representative Commodities (11) 
 Onion, green (10)
 Crop Group 03-07 : Bulb Vegetable Group (24) 
 Crop Group 03-07 Subgroup 3-07A : Onion, bulb, subgroup (19) 
 Crop Group 03-07 Subgroup 3-07A : Onion, bulb, subgroup: Representative Commodities (12) 
 Onion, bulb (12)
 Crop Group 03-07 Subgroup 3-07A : Onion, bulb, subgroup: Commodities (12) 
 Onion, bulb (12)
 Crop Group 03-07 Subgroup 3-07B : Onion, green, subgroup (16) 
 Crop Group 03-07 Subgroup 3-07B : Onion, green, subgroup: Representative Commodities (10) 
 Onion, green (10)
 Crop Group 03-07 Subgroup 3-07B : Onion, green, subgroup: Commodities (10) 
 Onion, green (10)
 Crop Group 04 : Leafy Vegetables (except Brassica Vegetables) Group (46) 
 Crop Group 04 Subgroup 4A : Leafy greens subgroup (18) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 04 Subgroup 4A : Leafy greens subgroup (6)
 Crop Group 04 Subgroup 4B : Leaf petioles subgroup (24) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 04 Subgroup 4B : Leaf petioles subgroup (10)
 Crop Group 05 : Brassica (Cole) Leafy Vegetables Group (48) 
 Crop Group 05 Subgroup 5A : Head & stem Brassica subgroup (37) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 05 Subgroup 5A : Head & stem Brassica subgroup (20)
 Crop Group 05 Subgroup 5B : Leafy Brassica greens subgroup (29) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 05 Subgroup 5B : Leafy Brassica greens subgroup (18)
 Crop Group 06 : Legume Vegetables (Succulent or Dried) Group (48) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 06 : Legume Vegetables (Succulent or Dried) Group: Soybean (8) 
 Soybean (8)
 Crop Group 06 Subgroup 6C : Dried shelled pea & bean (except soybean) subgroup (14) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 06 Subgroup 6C : Dried shelled pea & bean (except soybean) subgroup (10)
 Crop Group 08-10 : Fruiting Vegetable Group (54) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 08-10 : Fruiting Vegetable Group (34)
 Crop Group 09 : Cucurbit Vegetables Group (44) 
 Crop Group 09 Subgroup 9A : Melon subgroup (9) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 09 Subgroup 9A : Melon subgroup (5)
 Crop Group 09 Subgroup 9B : Squash/cucumber subgroup (15) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 09 Subgroup 9B : Squash/cucumber subgroup (3)
 Crop Group 12 : Stone Fruits Group (55) 
 Crop Group 12 : Stone Fruits Group: Representative Commodities (31) 
 Peach (26)
 Crop Group 12 : Stone Fruits Group: Commodities (33) 
 Peach (26)
 Crop Group 12-12 : Stone Fruit Group (39) 
 Crop Group 12-12 Subgroup 12-12B : Peach subgroup (28) 
 Crop Group 12-12 Subgroup 12-12B : Peach subgroup: Representative Commodities (26) 
 Peach (26)
 Crop Group 12-12 Subgroup 12-12B : Peach subgroup: Commodities (27) 
 Peach (26)
 Crop Group 13-07 : Berry & Small Fruit Crop Group (62) 
 Crop Group 13-07 Subgroup 13-07A : Caneberry subgroup (17) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 13-07 Subgroup 13-07A : Caneberry subgroup (12)
 Crop Group 13-07 Subgroup 13-07B : Bushberry subgroup (19) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 13-07 Subgroup 13-07B : Bushberry subgroup (13)
 Crop Group 13-07 Subgroup 13-07G : Low growing berry subgroup (45) 
 Crop Group 13-07 Subgroup 13-07G : Low growing berry subgroup: Representative Commodities (23) 
 Strawberry (23)
 Crop Group 13-07 Subgroup 13-07G : Low growing berry subgroup: Commodities (35) 
 Cranberry (27)
 Strawberry (23)
 Crop Group 13-07 Subgroup 13-07H : Low growing berry (except strawberry) subgroup (31) 
 Crop Group 13-07 Subgroup 13-07H : Low growing berry (except strawberry) subgroup: Representative Commodities (27) 
 Cranberry (27)
 Crop Group 13-07 Subgroup 13-07H : Low growing berry (except strawberry) subgroup: Commodities (28) 
 Cranberry (27)
 Crop Group 17 : Grass Forage, Fodder & Hay Group (42) 
 Crop Group 17 : Grass Forage, Fodder & Hay Group: Commodities (32) 
 Crop Group 17 : Grass Forage, Fodder & Hay Group: Commodities, forage (24) 
 Clover, forage (7)
 Crop Group 17 : Grass Forage, Fodder & Hay Group: Commodities, hay (31) 
 Clover, hay (7)
 Peanut, hay (19)
 Crop Group 18 : Nongrass Animal Feeds (Forage, Fodder, Straw & Hay) Group (31) 
 Crop Group 18 : Nongrass Animal Feeds (Forage, Fodder, Straw & Hay) Group: Representative commodities (21) 
 Alfalfa (21)
 Crop Group 18 : Nongrass Animal Feeds (Forage, Fodder, Straw & Hay) Group: Commodities (7) 
 Crop Group 18 : Nongrass Animal Feeds (Forage, Fodder, Straw & Hay) Group: Commodities, forage (7) 
 Clover, forage (7)
 Crop Group 18 : Nongrass Animal Feeds (Forage, Fodder, Straw & Hay) Group: Commodities, hay (7) 
 Clover, hay (7)
 Crop Group 19 : Herbs & Spices Group (12) 
 Crop Group 19 Subgroup 19A : Herb subgroup (10) 
 Cultivars, Varieties, and/or Hybrids of Crop Group 19 Subgroup 19A : Herb subgroup (8)
 Crop Group 20 : Oilseed Group (22) 
 Crop Group 20 Subgroup 20B : Sunflower subgroup (19) 
 Crop Group 20 Subgroup 20B : Sunflower subgroup: Representative Commodities (16) 
 Sunflower, seed (16)
03. Biological Effects of Specific Chemicals 
03. Biological Effects of Specific Chemicals
 biochemical uses [CHEBI:52206] (3306) 
 enzyme inhibitor [CHEBI:23924] (825) 
 acetyl-CoA carboxylase inhibitor [CHEBI:70722] (1) 
 clethodim [CHEBI:70721] (1)
05. Industrial Uses 
05. Industrial Uses
 pesticide [CHEBI:25944] (211) 
 herbicide [CHEBI:24527] (48) 
 clethodim [CHEBI:70721] (1)
08. Chemical Category 
08. Chemical Category
 main group molecular entity [CHEBI:33579] (25650) 
 s-block molecular entity [CHEBI:33674] (7287) 
 hydrogen molecular entity [CHEBI:33608] (6932) 
 hydroxides [CHEBI:24651] (5641) 
 organic hydroxy compound [CHEBI:33822] (3050) 
 enol [CHEBI:33823] (52) 
 clethodim [CHEBI:70721] (1)
 p-block molecular entity [CHEBI:33675] (25343) 
 halogen molecular entity [CHEBI:24471] (1475) 
 chlorine molecular entity [CHEBI:23117] (884) 
 organochlorine compound [CHEBI:36683] (543) 
 clethodim [CHEBI:70721] (1)
 halide [CHEBI:37578] (1402) 
 organohalogen compound [CHEBI:36684] (976) 
 organochlorine compound [CHEBI:36683] (543) 
 clethodim [CHEBI:70721] (1)
 chalcogen molecular entity [CHEBI:33304] (15225) 
 oxygen molecular entity [CHEBI:25806] (14414) 
 hydroxides [CHEBI:24651] (5641) 
 organic hydroxy compound [CHEBI:33822] (3050) 
 enol [CHEBI:33823] (52) 
 clethodim [CHEBI:70721] (1)
 organooxygen compound [CHEBI:36963] (11352) 
 ether [CHEBI:25698] (876) 
 oxime O-ether [CHEBI:36816] (32) 
 clethodim [CHEBI:70721] (1)
 carbonyl compound [CHEBI:36586] (5928) 
 ketone [CHEBI:17087] (1288) 
 cyclic ketone [CHEBI:3992] (644) 
 clethodim [CHEBI:70721] (1)
 diketone [CHEBI:46640] (53) 
 beta-diketone [CHEBI:67265] (31) 
 clethodim [CHEBI:70721] (1)
 sulfur molecular entity [CHEBI:26835] (1541) 
 sulfide [CHEBI:26822] (86) 
 organic sulfide [CHEBI:16385] (82) 
 clethodim [CHEBI:70721] (1)
 organosulfur compound [CHEBI:33261] (1005) 
 organic sulfide [CHEBI:16385] (82) 
 clethodim [CHEBI:70721] (1)
 organochalcogen compound [CHEBI:36962] (11874) 
 organosulfur compound [CHEBI:33261] (1005) 
 organic sulfide [CHEBI:16385] (82) 
 clethodim [CHEBI:70721] (1)
 organooxygen compound [CHEBI:36963] (11352) 
 ether [CHEBI:25698] (876) 
 oxime O-ether [CHEBI:36816] (32) 
 clethodim [CHEBI:70721] (1)
 carbonyl compound [CHEBI:36586] (5928) 
 ketone [CHEBI:17087] (1288) 
 cyclic ketone [CHEBI:3992] (644) 
 clethodim [CHEBI:70721] (1)
 diketone [CHEBI:46640] (53) 
 beta-diketone [CHEBI:67265] (31) 
 clethodim [CHEBI:70721] (1)
 carbon group molecular entity [CHEBI:33582] (23847) 
 organic molecular entity [CHEBI:50860] (23769) 
 heteroorganic entity [CHEBI:33285] (15197) 
 organohalogen compound [CHEBI:36684] (976) 
 organochlorine compound [CHEBI:36683] (543) 
 clethodim [CHEBI:70721] (1)
 organochalcogen compound [CHEBI:36962] (11874) 
 organosulfur compound [CHEBI:33261] (1005) 
 organic sulfide [CHEBI:16385] (82) 
 clethodim [CHEBI:70721] (1)
 organooxygen compound [CHEBI:36963] (11352) 
 ether [CHEBI:25698] (876) 
 oxime O-ether [CHEBI:36816] (32) 
 clethodim [CHEBI:70721] (1)
 carbonyl compound [CHEBI:36586] (5928) 
 ketone [CHEBI:17087] (1288) 
 cyclic ketone [CHEBI:3992] (644) 
 clethodim [CHEBI:70721] (1)
 diketone [CHEBI:46640] (53) 
 beta-diketone [CHEBI:67265] (31) 
 clethodim [CHEBI:70721] (1)
 organic hydroxy compound [CHEBI:33822] (3050) 
 enol [CHEBI:33823] (52) 
 clethodim [CHEBI:70721] (1)
 organic molecule [CHEBI:72695] (11399) 
 organic oxo compound [CHEBI:36587] (5932) 
 carbonyl compound [CHEBI:36586] (5928) 
 ketone [CHEBI:17087] (1288) 
 cyclic ketone [CHEBI:3992] (644) 
 clethodim [CHEBI:70721] (1)
 diketone [CHEBI:46640] (53) 
 beta-diketone [CHEBI:67265] (31) 
 clethodim [CHEBI:70721] (1)
 polyatomic entity [CHEBI:36357] (18777) 
 molecule [CHEBI:25367] (11520) 
 organic molecule [CHEBI:72695] (11399) 
 organic oxo compound [CHEBI:36587] (5932) 
 carbonyl compound [CHEBI:36586] (5928) 
 ketone [CHEBI:17087] (1288) 
 cyclic ketone [CHEBI:3992] (644) 
 clethodim [CHEBI:70721] (1)
 diketone [CHEBI:46640] (53) 
 beta-diketone [CHEBI:67265] (31) 
 clethodim [CHEBI:70721] (1)
 heteroatomic molecular entity [CHEBI:37577] (13672) 
 hydroxides [CHEBI:24651] (5641) 
 organic hydroxy compound [CHEBI:33822] (3050) 
 enol [CHEBI:33823] (52) 
 clethodim [CHEBI:70721] (1)
 halide [CHEBI:37578] (1402) 
 organohalogen compound [CHEBI:36684] (976) 
 organochlorine compound [CHEBI:36683] (543) 
 clethodim [CHEBI:70721] (1)
ChEBI Compound Accession Identifier:   [CHEBI:70721]
ChEBI Compound Description:   "An oxime O-ether resulting from the formal conversion ot the acyclic keto group of 5-[2-(ethylsulfanyl)propyl]-3-hydroxy-2-propionylcyclohex-2-en-1-one to the corresponding oxime with subsequent O-alkylation of the oxime by an (E)-3-chloroallyl group. It is used as a selective postemergence herbicide for the control of annual and perennial grasses in numerous crops, including alfalfa, celery, clover, conifers, cotton, cranberries, garlic, onions, ornamentals, peanuts, soybeans, strawberries, sugarbeet, sunflowers, and vegetables; the (-)-enantiomer has been reported to be more active than the (+)-enantiomer."
ChEBI Compound Identification Number:   70721
ChEBI InChI Value:   InChI=1S/C17H26ClNO3S/c1-4-14(19-22-8-6-7-18)17-15(20)10-13(11-16(17)21)9-12(3)23-5-2/h6-7,12-13,20H,4-5,8-11H2,1-3H3/b7-6+,19-14?
ChEBI InChIKey Value:   SILSDTWXNBZOGF-JWGBMQLESA-N
ChEBI Compound Name:   clethodim
ChEBI SMILES Value:   CCSC(C)CC1CC(=O)C(=C(O)C1)C(CC)=NOC\C=C\Cl
ChEBI Substance ID:   160646012
ChEBI URL:   ChEBI:70721
ChemSpider ID:   NS
Ontomatica Chemical Accession Key (OnChAKey):   SILSDTWXNBZOGF_JWGBMQLESA_N_000_000000
PubChem Compound ID:   6444391